When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | ClOOCl_Chen(2009)_200K_308,351nm(photodiss. cross sect.).txt |
NAME: | dichlorine dioxide, chlorine monoxide dimer, chlorine peroxide |
FORMULA: | ClOOCl |
AUTHOR(YEAR): | Chen(2009) |
T: | 200K |
λ: | 308,351nm(photodiss. cross sect.) |
BIBLIOGRAPHY: |
H.-Y. Chen, C.Y. Lien, W.-Y. Lin, Y.T. Lee, and J.J. Jim J. Lin, "UV absorption cross sections of ClOOCl are consistent with ozone degradation models",
Science 324, 781-784 (2009);
DOI: 10.1126/science.1171305
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COMMENTS: | Photodissociation cross section (Φσ), i.e., the product of the dissociation quantum yield Φ of ClOOCl (presumably = 1) and the ClOOCl absorption cross section σ (Φσ) has been determined using molecular beams with mass detection The value listed for 308 nm is the mean of (Φσ) = 4.911e-19 and 4.895e-19 determined with, respectively, Cl2 and Cl2O as the reference molecules The value listed for 351 nm is determined with Cl2 as the reference molecule |
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